The reactions of interaction of acetylene with water vapor, acetic acid and ammonia in the presence of heterogeneous catalysts have investigated. Depending on the nature of the starting components used, acetaldehyde and acetone, vinyl acetate, pyridine bases and pyrrole synthesized. Heterogeneous catalysts selected for each studied reaction based on some scientific prerequisites for the selection of catalysts. Active catalysts for the investigated reactions were determined, which contain compounds of cadmium, zinc, bismuth, chromium, iron and copper, in general, d-group metals. γ-Al2O3, bentonite and kaolin used as a catalyst carrier. Hydrofluoric acid, acetic acid, ammonium fluoride and others used for peptization. Some hypothetical mechanisms for the formation of target products for each reaction have proposed.
IKRAMOV, Abduvakhab; KHOLIKOVA, Sevara; and MUSULMANOV, Noryigit
"HETEROGENEOUS CATALYTIC CONVERSIONS OF ACETYLENE,"
CHEMISTRY AND CHEMICAL ENGINEERING: Vol. 2021
, Article 5.
Available at: https://uzjournals.edu.uz/cce/vol2021/iss2/5